Saturday, July 18, 2009

"Beryl"

Aquamarine and maxixe

Aquamarine (from Lat. aqua marina, "water of the sea") is a blue or turquoisevariety of beryl. It occurs at most localities which yield ordinary beryl, some of the finest coming from Russia. The gem-gravel placer deposits of Sri Lanka contain aquamarine. Clear yellow beryl, such as occurs in Brazil, is sometimes called aquamarine chrysolite. When corundum presents the bluish tint of typical aquamarine, it is often termed Oriental aquamarine. The deep blue version of aquamarine is called maxixe. Its color fades to white when exposed to sunlight or is subjected to heat treatment, though the color returns with irradiation.

The pale blue color of aquamarine is attributed to Fe2+. The Fe3+ ions produce golden-yellow color, and when both Fe2+ and Fe3+ are present, the color is a darker blue as in maxixe. Decoloration of maxixe by light or heat thus may be due to the charge transfer Fe3+ and Fe2+.[4][12][13][14] Dark-blue maxixe color can be produced in green, pink or yellow beryl by irradiating it with high-energy particles (gamma rays, neutrons or even X-rays).[15]

In the United States, aquamarines can be found at the summit of Mt. Antero in the Sawatch Range in central Colorado. In Wyoming, aquamarine has been discovered in the Big Horn mountains, near Powder River Pass. In Brazil, there are mines in the states of Minas Gerais,Espírito Santo and Bahia. The Mines of Colombia, Zambia, Madagascar, Malawi, Tanzaniaand Kenya also produce aquamarine.

The biggest aquamarine ever mined was found at the city of Marambaia, Minas Gerais, Brazil, in 1910. It weighed over 110 kg, and its dimensions were 48.5 cm long and 42 cm in diameter.

Culture usage

Emerald

Emerald refers to green beryl, colored by trace amounts of chromium and sometimes vanadium.[4][16] The word "emerald" comes from Latinsmaragdus, its original source being a Semitic word izmargad or theSanskrit word, marakata, meaning "green".[17] Most emeralds are highlyincluded, so their brittleness (resistance to breakage) is classified as generally poor.

Emeralds in antiquity were mined by the Egyptians and in Austria, as well as Swat in northernPakistan.[18] A rare type of emerald known as a trapiche emerald is occasionally found in the mines of Colombia. A trapiche emerald exhibits a "star" pattern; it has raylike spokes of dark carbon impurities that give the emerald a six-pointed radial pattern. It is named for thetrapiche, a grinding wheel used to process sugarcane in the region. Colombian emeralds are generally the most prized due to their transparency and fire. Some of the most rare emeralds come from three main emerald mining areas in Colombia: Muzo, Coscuez, and Chivor. Fine emeralds are also found in other countries, such as Zambia, Brazil, Zimbabwe, Madagascar,Pakistan, India, Afghanistan and Russia. In the US, emeralds can be found in Hiddenite, North Carolina. In 1998, emeralds were discovered in the Yukon.

Emerald is a rare and valuable gemstone and, as such, it has provided the incentive for developing synthetic emeralds. Both hydrothermal[19] and flux-growth synthetics have been produced. The first commercially successful emerald synthesis process was that of Carroll Chatham. The other large producer of flux emeralds was Pierre Gilson Sr., which has been on the market since 1964. Gilson's emeralds are usually grown on natural colorless beryl seeds which become coated on both sides. Growth occurs at the rate of 1 mm per month, a typical seven-month growth run producing emerald crystals of 7 mm of thickness.[20] The green color of emeralds is attributed to presense of Fe3+ and Fe2+ ions.[12] [13][14]

Goshenite

Crystal structure of beryl

Colorless beryl is called goshenite. The name originates from Goshen, Massachusetts where it was originally described. Since all these color varieties are caused by impurities and pure beryl is colorless, it might be tempting to assume that goshenite is the purest variety of beryl. However, there are several elements that can act as inhibitors to color in beryl and so this assumption may not always be true. The name goshenite has been said to be on its way to extinction and yet it is still commonly used in the gemstone markets. Goshenite is found to some extent in almost all beryl localities. In the past, goshenite was used for manufacturing eyeglasses and lenses owing to its transparency. Nowadays, it is most commonly used for gemstone purposes and also considered as a source of beryllium. [21][22]

The gem value of gohenite is relatively low. However, goshenite can be colored yellow, green, pink, blue and in intermediate colors by irradiating it with high-energy particles. The resoluting color depends on the content of Ca, Sc, Ti, V, Fe, and Co inmpurities.[12]

Golden beryl and heliodor

Golden beryl
Heliodor

Golden beryl can range in colors from pale yellow to a brilliant gold. Unlike emerald, golden beryl has very few flaws. The term "golden beryl" is sometimes synonymous with heliodor(from Greek helios "sun"), but golden beryl refers to pure yellow or golden yellow shades, while heliodor refers to the greenish-yellow shades. The golden yellow color is attributed to Fe3+ ions.[4][12] Both golden beryl and heliodor are used as gems. Probably the largest cut golden beryl is the flawless 2054 carat stone on display on display in the Hall of Gems,Washington, D.C.[23]


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