Opal
Opal is a mineraloid gel which is deposited at a relatively low temperature and may occur in the fissures of almost any kind of rock, being most commonly found with limonite, sandstone,rhyolite, marl and basalt. The word opal comes from the Latin opalus, by Greek opallios, and is from the same root as Sanskrit upálá[s] for "stone", originally a millstone with upárá[s] for slab.[4]
The water content is usually between three and ten percent, but can be as high as twenty percent. Opal ranges from clear through white, gray, red, orange, yellow, green, blue, magenta, rose, pink, slate, olive, brown, and black. Of these hues, the reds against black are the most rare, whereas white and greens are the most common. These color variations are a function of growth size into the red and infrared wavelengths. Opal is Australia's national gemstone.
| Opal | |
 An opal bracelet. The stone size is 18 by 15 mm (0.7 by 0.6 inch). | |
| General | |
|---|---|
| Category | Mineraloid |
| Chemical formula | Hydrated silica. SiO2·nH2O |
| Identification | |
| Color | White, black, red, orange, most of the full spectrum, colorless,iridescent |
| Crystal habit | Irregular veins, in masses, in nodules |
| Crystal system | Amorphous[1] |
| Cleavage | None[1] |
| Fracture | Conchoidal to uneven[1] |
| Mohs Scalehardness | 5.5–6.5[1] |
| Luster | Subvitreous to waxy[1] |
| Streak | White |
| Diaphaneity | opaque, translucent, transparent |
| Specific gravity | 2.15 (+.08, -.90)[1] |
| Polish luster | Vitreous to resinous[1] |
| Optical properties | Single refractive, often anomalous double refractive due to strain[1] |
| Refractive index | 1.450 (+.020, -.080) Mexican opal may read as low as 1.37, but typically reads 1.42–1.43[1] |
| Birefringence | none[1] |
| Pleochroism | None[1] |
| Ultravioletfluorescence | black or white body color: inert to white to moderate light blue, green, or yellow in long and short wave. May also phosphoresce; common opal: inert to strong green or yellowish green in long and short wave, may phosphoresce;fire opal: inert to moderate greenish brown in long and short wave, may phosphoresce.[1] |
| Absorption spectra | green stones: 660nm, 470nm cutoff[1] |
| Diagnostic features | darkening upon heating |
| Solubility | hot saltwater, bases, methanol,humic acid, hydrofluoric acid |
Precious opal
Precious opal shows a variable interplay of internal colors and even though it is a mineraloid, it does have an internal structure. At micro scales precious opal is composed of silica spheres some 150 to 300 nm in diameter in a hexagonal or cubic close-packed lattice. These ordered silica spheres produce the internal colors by causing the interference and diffraction of light passing through the microstructure of the opal.[5] It is the regularity of the sizes and the packing of these spheres that determines the quality of precious opal. Where the distance between the regularly packed planes of spheres is approximately half the wavelength of a component of visible light, the light of that wavelength may be subject to diffraction from thegrating created by the stacked planes. The spacing between the planes and the orientation of planes with respect to the incident light determines the colors observed. The process can be described by Bragg's Law of diffraction.
Visible light of diffracted wavelengths cannot pass through large thicknesses of the opal. This is the basis of the optical band gap in a photonic crystal, of which opal is the best known natural example. In addition, microfractures may be filled with secondary silica and form thin lamellae inside the opal during solidification. The term opalescence is commonly and erroneously used to describe this unique and beautiful phenomenon, which is correctly termedplay of color. Contrarily, opalescence is correctly applied to the milky, turbid appearance of common or potch opal. Potch does not show a play of color.
The veins of opal displaying the play of color are often quite thin, and this has given rise to unusual methods of preparing the stone as a gem. An opal doublet is a thin layer of opal, backed by a swart mineral such as ironstone, basalt, or obsidian. The darker backing emphasizes the play of color, and results in a more attractive display than a lighter potch.
Combined with modern techniques of polishing, doublet opal produces similar effect of black or boulder opals at a mere fraction of the price. Doublet opal also has the added benefit of having genuine opal as the top visible and touchable layer, unlike triplet opals.
The triplet-cut opal backs the colored material with a dark backing, and then has a domed cap of clear quartz or plastic on top, which takes a high polish and acts as a protective layer for the relatively fragile opal. The top layer also acts as a magnifier, to emphasise the play of color of the opal beneath, which is often of lower quality. Triplet opals therefore have a more artificial appearance, and are not classed as precious opal.
Common opal
Besides the gemstone varieties that show a play of color, there are other kinds of common opal such as the milk opal, milky bluish to greenish (which can sometimes be of gemstone quality), resin opal which is honey-yellow with a resinous luster, wood opal which is caused by the replacement of the organic material in wood with opal[6], menilite which is brown or grey,hyalite is a colorless glass-clear opal sometimes called Muller's Glass, geyserite, also calledsiliceous sinter, deposited around hot springs or geysers and diatomite or diatomaceous earth, the accumulations of diatom shells or tests.
Other varieties of opal
Fire opals are transparent to translucent opals with warm body colors yellow, orange, orange-yellow or red and they do not show any play-of-color.. The most famous source of fire opals is the state of Queretaro in Mexico and these opals are commonly called Mexican fire opals.
Peruvian opal (also called blue opal) is a semi-opaque to opaque blue-green stone found in Peru which is often cut to include the matrix in the more opaque stones. It does not display pleochroism.
Sources of opal
Australia produces around 97% of the world’s opal. 90% is called ‘light opal’ or white and crystal opal. White makes up 60% of the opal productions but cannot be found in all of the opal fields. Crystal opal or pure hydrated silica makes up 30% of the opal produced, 8% is black and only 2% is boulder opal.[citation needed]
The town of Coober Pedy in South Australia is a major source of opal. Andamooka in South Australia is also a major producer of matrix opal, crystal opal, and black opal. Another Australian town, Lightning Ridge in New South Wales, is the main source of black opal, opal containing a predominantly dark background (dark-gray to blue-black displaying the play of color). Boulder opal consists of concretions and fracture fillings in a dark siliceous ironstonematrix. It is found sporadically in western Queensland, from Kynuna in the north, to Yowah and Koroit in the south.[7]
The Virgin Valley opal fields of Humboldt County in northern Nevada produce a wide variety of precious black, crystal, white, fire, and lemon opal. The black fire opal is the official gemstone of Nevada. Most of the precious opal is partial wood replacement. Miocene age opalised teeth, bones, fish, and a snake head have been found. Some of the opal has high water content and may desiccate and crack when dried. The largest black opal in the Smithsonian Museumcomes from the Royal Peacock opal mine in the Virgin Valley.[citation needed]
Another source of white base opal in the United States is Spencer, Idaho. A high percentage of the opal found there occurs in thin layers. As a result, most of the production goes into the making of doublets and triplets.
Other significant deposits of precious opal around the world can be found in the Czech Republic, Slovakia, Hungary, Turkey, Indonesia, Brazil, Honduras, Guatemala, Nicaragua and Ethiopia.
In late 2008, NASA announced that it had discovered opal deposits on Mars.[8]
Synthetic opal
As well as occurring naturally, opals of all varieties have been synthesized experimentally and commercially. The discovery of the ordered sphere structure of precious opal led to its synthesis by Pierre Gilson in 1974.[5] The resulting material is distinguishable from natural opal by its regularity; under magnification, the patches of color are seen to be arranged in a "lizard skin" or "chicken wire" pattern. Synthetics are further distinguished from naturals by the former's lack of fluorescence under UV light. Synthetics are also generally lower in density and are often highly porous.
Two notable producers of synthetic opal are the companies Kyocera and Inamori of Japan. Most so-called synthetics, however, are more correctly termed "imitation opal", as they contain substances not found in natural opal (e.g., plastic stabilizers). The imitation opals seen in vintage jewelry are often "Slocum Stone" consisting of laminated glass with bits of foil interspersed.
Local atomic structure of opals
The lattice of spheres of opal that cause the interference with light are several hundred times larger than the fundamental structure of crystalline silica. As a mineraloid, there is no unit cellthat describes the structure of opal. Nevertheless, opals can be roughly divided into those that show no signs of crystalline order (amorphous opal) and those that show signs of the beginning of crystalline order, commonly termed cryptocrystalline or microcrystalline opal.[9]Dehydration experiments and infrared spectroscopy have shown that most of the H2O in the formula of SiO2·nH2O of opals is present in the familiar form of clusters of molecular water. Isolated water molecules, and silanols, structures such as Si-O-H, generally form a lesser proportion of the total and can reside near the surface or in defects inside the opal.
The structure of low-pressure polymorphs of anhydrous silica consist of frameworks of fully-corner bonded tetrahedra of SiO4. The higher temperature polymorphs of silica cristobalite andtridymite are frequently the first to crystallize from amorphous anhydrous silica, and the local structures of microcrystalline opals also appear to be closer to that of cristobalite andtridymite than to quartz. The structures of tridymite and cristobalite are closely related and can be described as hexagonal and cubic close-packed layers. It is therefore possible to have intermediate structures in which the layers are not regularly stacked.
Microcrystalline opal
Opal-CT has been interpreted as consisting of clusters of stacking of cristobalite and tridymite over very short length scales. The spheres of opal in opal-CT are themselves made up of tiny microcrystalline blades of cristobalite and tridymite. Opal-CT has occasionally been further subdivided in the literature. Water content may be as high as 10 wt%. Lussatite is a synonym. Opal-C, also called Lussatine, is interpreted as consisting of localized order of α-cristobalite with a lot of stacking disorder. Typical water content is about 1.5wt%.
Non-crystalline opal
Two broad categories of non-crystalline opals, sometimes just referred to as "opal-A", have been proposed. The first of these is opal-AG consisting of aggregated spheres of silica, with water filling the space in between. Precious opal and potch opal are generally varieties of this, the difference being in the regularity of the sizes of the spheres and their packing. The second "opal-A" is opal-AN or water-containing amorphous silica-glass. Hyalite is another name for this.
Non-crystalline silica in siliceous sediments is reported to gradually transform to opal-CT and then opal-C as a result of diagenesis, due to the increasing overburden pressure insedimentary rocks, as some of the stacking disorder is removed.[10]
Historical superstitions
In the Middle Ages, opal was considered a stone that could provide great luck because it was believed to possess all the virtues of each gemstone whose color was represented in the color spectrum of the opal.[11] Victorian superstitions were created by the established gem dealers to stop the rush to buy opals. They paid an author to attribute bad luck to the stone, though some believed this is avoided if opal is the owner's birthstone or if the stone was a gift. Even as recently as under the last czar at the beginning of the 20th century, it was believed that when a Russian of any rank saw an opal among other goods offered for sale, he or she should not buy anything more since the opal was believed to embody the evil eye.[11] Opal is considered the birthstone for people born in October.
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